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Crystallographic and magnetic study of (Sm/Gd)2Fe17-xCox solid solutions

Identifieur interne : 000B37 ( Main/Exploration ); précédent : 000B36; suivant : 000B38

Crystallographic and magnetic study of (Sm/Gd)2Fe17-xCox solid solutions

Auteurs : M. S. Ben Kraiem [Tunisie] ; M. Ellouze [Tunisie] ; A. Cheikhrouhou [Tunisie] ; Ph. L'Heritier [France]

Source :

RBID : Pascal:03-0076356

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English descriptors

Abstract

The structural and magnetic properties of (Sm/Gd)2Fe17-xCox (0 < x < 3) solid solutions have been investigated using X-ray diffraction and magnetic measurements. All the compounds investigated have the rhombohedral Th2Zn17-type structure. The unit cell parameters of the substituted samples are modified compared to the parent (Sm/Gd)2Fe17 compounds. The Curie temperatures (Tc) of Sm1.5Gd0.5Fe17-xCox intermetallics are higher than the parent sample (Sm1.5Gd0.5Fe17). For example, Tc of Sm1.5Gd0.5Fe14Co3 (689 K) is approximately 283 K higher than that of Sm1.5Gd0.5Fe17. The saturation magnetization of Sm1.5Gd0.5Fe17-xCox, obtained at room temperature, increases with increasing Co content.


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Le document en format XML

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Co
<sub>x</sub>
solid solutions</title>
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<term>Cobalt alloys</term>
<term>Curie point</term>
<term>Experimental study</term>
<term>Gadolinium alloys</term>
<term>Intermetallic compounds</term>
<term>Iron alloys</term>
<term>Lattice parameters</term>
<term>Magnetization</term>
<term>Quantity ratio</term>
<term>Quaternary alloys</term>
<term>Samarium alloys</term>
<term>Solid solutions</term>
<term>XRD</term>
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<keywords scheme="Pascal" xml:lang="fr">
<term>Diffraction RX</term>
<term>Paramètre cristallin</term>
<term>Point Curie</term>
<term>Aimantation</term>
<term>Etude expérimentale</term>
<term>Effet concentration</term>
<term>Solution solide</term>
<term>Composé intermétallique</term>
<term>Samarium alliage</term>
<term>Gadolinium alliage</term>
<term>Fer alliage</term>
<term>Cobalt alliage</term>
<term>Alliage quaternaire</term>
<term>Alliage SmGdFeCo</term>
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<div type="abstract" xml:lang="en">The structural and magnetic properties of (Sm/Gd)
<sub>2</sub>
Fe
<sub>17-x</sub>
Co
<sub>x</sub>
(0 < x < 3) solid solutions have been investigated using X-ray diffraction and magnetic measurements. All the compounds investigated have the rhombohedral Th
<sub>2</sub>
Zn
<sub>17</sub>
-type structure. The unit cell parameters of the substituted samples are modified compared to the parent (Sm/Gd)
<sub>2</sub>
Fe
<sub>17</sub>
compounds. The Curie temperatures (T
<sub>c</sub>
) of Sm
<sub>1.5</sub>
Gd
<sub>0.5</sub>
Fe
<sub>17-x</sub>
Co
<sub>x</sub>
intermetallics are higher than the parent sample (Sm
<sub>1.5</sub>
Gd
<sub>0.5</sub>
Fe
<sub>17</sub>
). For example, T
<sub>c</sub>
of Sm
<sub>1.5</sub>
Gd
<sub>0.5</sub>
Fe
<sub>14</sub>
Co
<sub>3</sub>
(689 K) is approximately 283 K higher than that of Sm
<sub>1.5</sub>
Gd
<sub>0.5</sub>
Fe
<sub>17</sub>
. The saturation magnetization of Sm
<sub>1.5</sub>
Gd
<sub>0.5</sub>
Fe
<sub>17-x</sub>
Co
<sub>x</sub>
, obtained at room temperature, increases with increasing Co content.</div>
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